中文摘要：

巯基-乙烯基加成反应具有清洁、高效、条件温和的特点，广泛应用于有机合成、聚合物科学和材料化学等诸多领域。国内外关于这一反应的研究已有大量文献报道，但该反应在含硅聚合物的合成与应用研究中还少有触及。本文综述了巯基一乙烯基加成反应在聚硅氮烷、聚硅碳烷、聚硅氧烷三种含硅聚合物合成中的应用，介绍了国内外的研究现状及发展趋势，并对硅基聚合物中的巯基一乙烯基加成反应的反应机理、动力学特征及其潜在应用领域进行了概述。

英文摘要：

The thiol-ene addition reaction applications in organic synthesis, polymer and about this reaction,but which has been used is a clean, efficient, robust and mild method with wide materials chemistry. Till now, there are a lot of references rarely in organosilicon and this micro-review summarizes the reports that describe the thiol-ene reactions and polysilazane. The mechanism, kinetics and were overviewed as well. of vinylsilanes prepared in polycarbosilane,polysiloxane its potential applications of thiol-ene addition reaction