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连铸Ag-28Cu-0.75Ni合金相组成、组织及性能
  • ISSN号:0258-7076
  • 期刊名称:《稀有金属》
  • 时间:0
  • 分类:TK91[动力工程及工程热物理]
  • 作者机构:昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室,云南昆明650106
  • 相关基金:国家自然科学基金项目(51267007);云南省院所技术开发专项(2013DC016);云南省院省校科技合作项目(2015IB012);院士专家工作站项目(2015IC046)资助
中文摘要:

采用连续铸造技术制备Ag-28Cu-0.75Ni(%,原子分数)合金棒材,真空退火后进行冷拉拔加工,分别采用X射线衍射(XRD)、金相显微镜(OM)和扫描电镜(SEM)对合金的物相、铸态、加工态和断口组织进行表征,并对导电率、硬度、强度和延伸率进行测试。结果表明:Ag-28Cu-0.75Ni的显微组织为:以Ag,Ni为溶质的Cu相固溶体,以Cu为溶质的Ag相固溶体和共晶(Ag+Cu)结构;其连铸态微观结构为典型的表面细晶区、柱状晶区和中心等轴层片状晶区三区结构,铸锭中散落着形貌清晰、形态规整的枝晶,枝晶偏析以及中心等轴区的边界偏析造成易腐蚀的低熔点区域。同时,材料本身加工态横截面晶粒细化、组织均匀,纵截面晶粒由点块状变为纤维状,发生择优取向形成形变织构。随真应变的增加,强度、硬度随之增加,而导电率、延伸率下降。

英文摘要:

The Ag-28Cu-0.75Ni( % , atom fraction) alloy bars were processed by cold drawing after vacuum annealing which were produced by continuous casting technology. The phases, cast states, working states and fracture morphologies were characterized by X- ray diffraction (XRD) , metalloscope and scanning electron microscopy ( SEM ) , respectively. At the same time, the electrical conduc- tivity, hardness, strength and elongation were tested. The results showed that Ag and Ni were solid dissolved in Cu phase solid solu- tion, Cu was solid dissolved in Ag phase solid solution and eutectic structure ( Ag + Cu) was also found. The microstructures of casting state alloy included surface fine grain area, columnar grain zone and center equiaxed lamellar crystal region that were typical three - zone structures. The dendrites which were of clear and regular shape morphology were scattered in the ingot. However, the corrosion of low melting point was easily led by dendrite segregation and boundary segregation of center equiaxial c17stal zone. Grain refinement process appeared in the cross section and its organization became homogeneous; for the longitudinal section grain, the shape changed from point to fibrous lumps, generated preferred orientation and formed deformation texture. The strength and hardness of the alloy in- creased with the true strain increasing, while the conductivity and elongation reduced.

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688