采用高温固相反应方法在空气中制备了Sr2SiO4∶Dy^3+发光材料。在365 nm紫外光激发下,测得Sr2SiO4∶Dy^3+材料的发射光谱为一多峰宽谱,发射峰分别位于486,575和665 nm处。研究了电荷补偿剂Li^+,Na^+和K^+对Sr2SiO4∶Dy^3+材料发射光谱强度的影响,结果显示,不同电荷补偿剂下,随电荷补偿剂掺杂浓度的增大,Sr2SiO4∶Dy^3+材料发射光谱强度的演化趋势相同,即,Sr2SiO4∶Dy^3+材料发射峰强度先增大后减小,但不同电荷补偿剂下,材料发射峰强度最大处对应的补偿剂浓度不同,对应Li^+,Na^+和K^+时,浓度分别为4 mol%,3 mol%和3 mol%。同时,对研究结果进行了理论分析。
The Sr2SiO4∶Dy^3+ phosphor was synthesized by the high temperature solid-state reaction method in air.Dy2O3(99.9%),SiO2(99.9%),SrCO3(99.9%),Li2CO3(99.9%),Na2CO3(99.9%) and K2CO3(99.9%) were used as starting materials,and the Dy^3+ doping concentration was 2 mol%.The emission spectrum was measured by a SPEX1404 spectrophotometer,and all the characterization of the phosphors was conducted at room temperature.The emission spectrum of Sr2SiO4∶Dy^3+ phosphor showed several bands centered at 486,575 and 665 nm under the 365 nm excitation.The effect of Li^+,Na^+ and K^+ on the emission spectra of Sr2SiO4∶Dy^3+ phosphor was studied.The results show that the location of the emission spectrum of Sr2SiO4∶Dy^3+ phosphor was not influenced by Li^+,Na^+ and K^+.However,the emission spectrum intensity was greatly influenced by Li^+,Na^+ and K^+,and the evolvement trend was monotone with different charge compensation,i.e.the emission spectrum intensity of Sr2SiO4∶Dy^3+ phosphor firstly increased with increasing Li^+ concentration,then decreased.However the charge compensation concentration corresponding to the maximum emission intensity was different with different charge compensation,and the concentration is 4,3 and 3 mol% corresponding to Li^+,Na^+ and K^+,respectively.And the theoretical reason for the above results was analyzed.