用表面张力、电导和法荧光光度法测定了阳离子表面活性剂3-对壬基酚基-2-羟丙基三甲基溴化铵(NPTAX,X=Cl,Br,I)的胶束化行为.根据实验数据及相应的公式确定出临界胶束浓度(cmc)、胶束聚集Gibbs自由能(△Gm),临界胶束浓度时的胶束解离度(a^0)和胶束聚集数.考察了温度、浓度和反离子对这些参数的影响.
The detailed micellization behavior of cationic surfaetants 3-p-nonylphenoxy-2- hydroxypropyl trimethyl ammonium halide (NPTAX, X = Cl, Br, I) was studied by surface tension, conductivity and steady-state fluorescence measurements in the temperature range of 15 to 50 ℃. The critical micelle concentrations (cmc), thermodynamics of mieellization (△Gm), degree of counterion dissociation (a^0) at the eme and aggregation number (Nagg) were determined from experimental data. The effects of temperature and concentrations of surfactant on their various properties in aqueous solution have been investigated, respectively.