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中文摘要：
5-氨基四氮唑（HATZ）与硝酸锌通过溶剂热反应得到了一个新的化合物[Zn（ATZ）2].DMA（1）,对其进行了X射线粉末衍射、红外光谱和元素分析表征.单晶X射线衍射分析表明,该化合物展示了一个四连接金刚烷拓扑的三维微孔金属有机框架,沿[100]方向的孔道维度大约为1.27 nm×0.89 nm,PLATON计算结果表明,孔体积为53.5%.此外,荧光光谱测试结果表明,化合物在室温下具有较强的蓝色荧光性质.
英文摘要：
A self-assembly reaction between the ligand 5-amino-tetrazole（HATZ） and zinc（Ⅱ） nitrate led to the formation of Zn（ATZ）2·DMA（1）,which was characterized by X-ray powder diffraction（XRPD）,IR spectrum and elemental analysis.Single-crystal X-ray analysis indicates that compound 1 exhibits a 3D microporous diamondoid（dia） topology with a channel dimension of about 1.27 nm×0.89 nm along the direction.PLATON calculations show a void space of ca.53.5% per unit cell.The luminescent spectrum of compound 1 shows a strong blue fluorescence at room temperature.
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