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中文摘要：
利用常规合成方法合成了1个夹心型锑钨酸盐H4.8{Mn（H2O）4}2[{Mn（H2O）2}2{Mn2-（H2O）4}0.8{W2（H2O）2（OH）2}0.2（B-β-SbW9O33）2]·16H2O（1）,对其进行了红外光谱和热重表征,并测定了晶体结构.晶体衍射数据显示,该化合物属于三斜晶系,P-1空间群,a=13.3636（17）,b=14.1137（18）,c=14.1369（18）,α=95.989（2）°,β=106.839（2）°,γ=103.708（2）°,V=2436.1（5）3,Z=1,Rl=0.0652,wR2=0.1564.晶体解析表明,化合物1中夹心型锑钨酸盐多阴离子通过过渡金属Mn2＋离子共价连接成2-D层状结构.
英文摘要：
Sandwich-type tungstoantimonate was synthesized via aqueous solution synthesis. We structurally characterized the compound using elemental analysis, infrared spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. The results suggested that the compound is a triclinic system with a P-1 space group. The two-dimensional layered structure was formed through covalent bonding interactions between the sandwich-type polyoxoanion and the Mn2＋ cations.
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