将石墨烯电极与离子液体N-甲基-N-丙基吡咯烷氰酸盐([C3mpyr][OCN])/碳酸丙烯酯(PC)混合电解液组装成超级电容器,采用循环伏安(CV)、交流阻抗(EIS)、恒电流充放电(GCD)等方法研究了其在50、60、70℃环境下的电化学性能。结果表明:该体系在较高温度下的电化学性能优异,70℃下其比容量最高可达295 F·g(-1),能量密度可达118 W·h·kg(-1),且恒电流充放电循环稳定性较好。
Supercapacitors were constructed with graphene as electrodes and ionic liquid N-methyl-Npropylpyrrolidinium cyanate([C3mpyr] [OCN])/propylene carbonate(PC) as the mixed electrolytes. The electrochemical properties of constructed supercapacitors were tested at 50, 60 and 70℃ by cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge(GCD). The results indicated that the constructed supercapacitors exhibited good electrochemical properties at high operating temperatures. The supercapacitors gave the specific capacity of 295 F·g(-1) and delivered an energy density as high as 118 W·h·kg(-1) at 70℃ with the current density of 0.5 A·g(-1). Additionally, the constructed supercapacitors showed a good cycling stability.