合成了一系列功能化酸性离子液体并用于模拟油品中非碱性氮-吲哚的脱除。结果表明,离子液体的阴离子对脱氮率有较大影响,离子液体的酸性越强,对吲哚的选择性脱除效果越好,不同阴离子的脱氮率顺序为:HSO4- 〉 CF3COO- 〉 H2PO4- 〉 CH3COO-。以(CH3CH2)3N(CH2)3SO3HHSO4为例,考察了剂油比、剂水比、沉降时间、反应时间和温度对油品脱氮率的影响。结果表明,在优化的工艺路线下,(CH3CH2)3N(CH2)3SO3HHSO4对油品中的吲哚脱除率可达99.12%,重复使用六次后,脱氮活性未见明显降低,具有良好的稳定性,。
A series of functionalized acidic ionic liquids (ILs) were synthesized and used to remove non-basic nitrogen (indole) in model oil. The results indicate that the anions have a significant impact on the denitrification efficiency; the denitrification rate of the ionic liquids with various anions increases with their acidity, i.e. it follows the order of HSO4- 〉 CF3COO- 〉 H2PO4- 〉 CH3COO-. The effects of IL/oil ratio, IL/H2O ratio, settlement time, reaction temperature and time on the denitrification efficiency of (CH3CH2)3 N (CH2)3SO3H HSO4 were well considered. The results showed that 99.12% indole nitrogen in the oil can be removed with (CH3CH2)3N(CH2)3SO3HHSO4 under the optimum condition; furthermore, the IL exhibits high stability and its denitrification activity remains almost unchanged even after being reused for six times.