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干摩擦条件下丁腈橡胶和氟橡胶摩擦磨损行为研究
  • ISSN号:1000-890X
  • 期刊名称:《橡胶工业》
  • 时间:0
  • 分类:TQ333.7[化学工程—橡胶工业] TQ333.93[化学工程—橡胶工业]
  • 作者机构:[1]沈阳工程学院机械学院,辽宁沈阳110136, [2]沈阳工业大学机械工程学院,辽宁沈阳110870, [3]辽宁建筑职业学院,辽宁辽阳111000
  • 相关基金:国家自然科学基金资助项目(50875178); 辽宁省教育厅科技计划资助项目(200814122)
中文摘要:

采用微机控制磨粒磨损试验机研究丁腈橡胶(NBR)和氟橡胶(FKM)与45^#钢配副在干摩擦条件下的摩擦磨损行为,并对NBR和FKM的磨痕表面形貌、元素含量和表面官能团变化进行分析。结果表明:当转速较低时,NBR和FKM均以磨粒磨损(微切削)为主;当转速大于200 r·min^-1时,NBR磨痕表面出现胶合现象,表现为粘着磨损,FKM的耐磨性能优于NBR。NBR和FKM的磨粒磨损机理相似,主要物理过程为宏观分层剥落;当转速较高时,橡胶/钢副接触面发生了粘着转移,在钢环表面形成了转移膜。在干摩擦过程中NBR和FKM的分子链发生断裂形成大分子自由基,大分子自由基异构化并发生氧化反应。

英文摘要:

In this study,the wear mechanism of NBR and FKM against 45^# steal surface under dry sliding was investigated by using microcomputer controlled abrasion testing machine.The change of surface morphology,element content and functional group on the abraded surface of NBR and FKM before and after wear was analyzed.The results showed that,the wear mechanism of NBR and FKM were mainly abrasive wear(micro cutting) at low rotation rate,and when the rotation rate was higher than 200 r · min^-1,scuffing phenomenon on the worn surface of NBR began to appear,indicating that the wear mechanism was adhesive wear.It was found that the wear resistance of FKM was better than that of NBR.The abrasive wear mechanism for NBR and FKM was similar,and the main physical processes of wear were the macro delamination.At high rotation rate,there was an adhesive transfer between rubber/steel contact surface,and transfer film formed on the steel surface.In the dry friction process,molecular chains of NBR and FKM were broken,the macromolecular radicals were formed and isomerized,and oxidation reactions occurred.

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期刊信息
  • 《橡胶工业》
  • 中国科技核心期刊
  • 主管单位:中国石油和化工协会
  • 主办单位:北京橡胶工业研究设计院
  • 主编:黄丽萍
  • 地址:北京市海淀区阜石路甲19号
  • 邮编:100143
  • 邮箱:rubbertire@263.net
  • 电话:010-51338149 51338490
  • 国际标准刊号:ISSN:1000-890X
  • 国内统一刊号:ISSN:11-1812/TQ
  • 邮发代号:2-380
  • 获奖情况:
  • 2011年全国石油和化工行业优秀报刊一等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国高分子图书馆,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:7750