欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以TiCl4蒸气处理深度脱铝的丝光沸石,采用气固相同晶置换制备了含钛丝光沸石（Ti-MOR）,并以H2O2作为氧化剂,考察了釜式反应器中Ti-MOR催化甲乙酮（MEK）与氨的液相氨氧化反应合成甲乙酮肟（MEKO）的性能,进而在连续淤浆床反应器中评价了Ti-MOR的稳定性和选择性.结果表明,在优化的反应条件下,Ti-MOR催化剂上MEK连续氨氧化反应的转化率和MEKO选择性分别达到95%和99%以上,优于传统的钛硅分子筛TS-1;同时,MEK转化率、MEKO选择性、催化剂耐积炭性以及稳定性等指标接近结构重排改性的Ti-MWW催化剂.
英文摘要：
The liquid-phase ammoximation of methyl ethyl ketone（MEK） to methyl ethyl ketone oxime（MEKO） with ammonia and hydrogen peroxide was conducted over MOR-type titanosilicate（Ti-MOR）,which was prepared from highly dealuminated mordenite and TiCl4 vapor by a secondary method of gas-solid phase reaction.The effects of reaction parameters on this reaction were studied systematically in a bath-type reactor.Based on the optimized reaction conditions,Ti-MOR was further employed as the catalyst for the ammoximation of MEK to MEKO in a continuous slurry reactor.This catalyst exhibited good catalytic activity and excellent MEKO selectivity in comparison to TS-1.Moreover,in terms of ketone conversion,oxime selectivity,coke resistance,and lifetime,Ti-MOR possessed the same advantages as the Ti-MWW catalyst prepared by structural rearrangement.
同期刊论文项目
同项目期刊论文
Synthesis, Characterization, and Catalytic Properties of Interlayer Expanded Aluminosilicate IEZ-PLS
Efficient cycloaddition of epoxides and carbon dioxide over novel organic-inorganic hybrid zeolite c
Hierarchical, core-shell meso-ZSM-5@mesoporous aluminosilicate-supported Pt nanoparticles for bifunc
Palladium phthalocyaninesulfonate functionalized mesoporous polymer: A highly efficient photocatalys
Intermolecular condensation of ethylenediamine to 1,4-diazabicyclo(2,2,2)octane over H-ZSM-5 catalys
Synthesis and formation mechanism of TS-1@mesosilica core-shell materials templated by triblock copo
Hydrothermal synthesis of MWW-type stannosilicate and its post-structural transformation to MCM-56 a
Post-synthesis, characterization and catalytic properties of fluorine-planted MWW-type titanosilicat
One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica
Distinctions of Hydroxylamine Formation and Decomposition in Cyclohexanone Ammoximation over Micropo
Post-Synthesis Treatment Gives Highly Stable Siliceous Zeolites through the Isomorphous Substitution
Postsynthesis of mesoporous MOR-type titanosilicate and its unique catalytic properties in liquid-ph
An Efficient and Recyclable Mesostructured Polymer-Supported N-Heterocyclic Carbene-Palladium Cataly
Synthesis of core-shell structured TS-1@mesocarbon materials and their applications as a tandem cata
Highly Selective Liquid-Phase Oxidation of Cyclohexane to KA Oil over Ti-MWW Catalyst: Evidence of F
Multilayer structured MFI-type titanosilicate: Synthesis and catalytic properties in selective epoxi
Trimodel hierarchical yolk-shell porous materials TS-1@mesocarbon: Synthesis and catalytic applicati
Hydrothermal synthesis of MWW-type analogues using linear-type quaternary alkylammonium hydroxides a
Core/shell-structured TS-1@mesoporous silica-supported Au nanoparticles for selective epoxidation of
Fluorine-planted titanosilicate with enhanced catalytic activity in alkene epoxidation with hydrogen
Core/shell-structured Al-MWW@B-MWW zeolites for shape-selective toluene disproportionation to para-x
Synthesis of Mesoporous TS-1 Zeolite Microspheres and Catalytic Property in Cyclohexanone Ammoximati
Mesoporus MCM-22 Zeolites Prepared through Organic Amine-Assisted Reversible Structural Change and P
期刊信息
位置：