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Keggin型杂多阴离子模板诱导超分子包容结构的构建及性质研究
  • ISSN号：1000-5854
  • 期刊名称：河北师范大学学报(自然科学版)
  • 时间：0
  • 页码：310-314
  • 语言：中文
  • 分类：O614.61[理学—无机化学;理学—化学]
  • 作者机构：[1]河北师范大学化学与材料科学学院,河北石家庄050016, [2]河北师范大学实验中心,河北石家庄050016
  • 相关基金：国家自然科学基金（20701011）; 河北省教育厅科研基金（Z2006436）; 河北师范大学博士启动基金（L2005B13）
  • 相关项目：多金属氧簇诱导的吡啶类配体原位反应机理研究
作者： 吴晶晶|王彦娜|韩占刚|翟学良|郝青华|
关键词： 水热合成, 多金属氧酸盐, 氢键, 阴离子模板作用, hydrothermal synthesis, polyoxometalate, hydrogen bond, anionic template
中文摘要：

以饱和磷钨酸为原料,溶剂热条件下合成了[HN（C2H5）3]3[N（C2H5）3]2H2[PW12O40].2H2O,这是一例基于Keggin型阴离子的包容结构化合物.X射线单晶衍射表征该晶体结构中Keggin型阴离子起到了模板诱导作用,通过有方向性的氢键作用力引导有机胺分子有序排列构成了无机-有机超分子包容结构.同时对该化合物进行了元素分析、IR,UV,XPS,XRD,TG-DTG以及电化学等性质的研究.

英文摘要：

A new polyoxometalate,formulated [HN（C2H5）3]3[N（C2H5）3]2[PW12O40]·2H2O（1） has been hydrothermally synthesized.Single crystal X-ray diffraction analysis shows that structure-directing template effect of inorganic anions play an important role in the self-organization process of these subunits.Compound 1 has been characterized by elemental analysis,IR,TG,UV,TG-DTG,XRD and electrochemical research.

同期刊论文项目
多金属氧簇诱导的吡啶类配体原位反应机理研究
期刊论文 42 会议论文 6
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期刊信息
  • 《河北师范大学学报：自然科学版》
  • 中国科技核心期刊
  • 主管单位:河北省教育厅
  • 主办单位:河北师范大学
  • 主编：蒋春澜
  • 地址：河北省石家庄市南二环东路20号
  • 邮编：050024
  • 邮箱：ziranb@mail.hebtu.edu.cn
  • 电话：0311-80786364
  • 国际标准刊号：ISSN：1000-5854
  • 国内统一刊号：ISSN：13-1061/N
  • 邮发代号:18-201
  • 获奖情况:
  • 全国优秀科技期刊,华北优秀科技期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,美国数学评论（网络版）,德国数学文摘,英国动物学记录,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）
  • 被引量:6209