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中文摘要：
纳米级尺度结构的多金属氧簇（多酸，多阴离子簇，POMs）具备优异的氧化还原催化和酸催化双功能性质特点，可催化多种有机反应。把其引入到溶剂热原位反应中，有望进一步展示其优异性质，诱使新奇有机反应的进行。吡啶类有机分子是良好的光学材料，较强的配位能力和在溶剂热条件下的原位反应活性使其已成为构筑无机-有机新型复合材料和新颖结构配合物的重要反应物。本项目在晶体工程理论和分子材料设计的思想指导下，探究溶剂热条件下多金属氧簇诱导的多吡啶类配体原位反应特点，探究反应的历程。主要工作为a) 系统研究了多种多酸簇和有机吡啶类分子体系的结构双重互选组装；b) 对经典多酸阴离子簇结构表面进行修饰，得到了多种{VO5}/{SbO4}/{CuO4N2}帽式Keggin结构；c) 多阴离子可以和有机分子间通过方向性的氢键，卤键和芳环堆积作用力而相互有序排列；d) 结果发现六元环{VO}6型Sandwich结构可诱发新的C-C键耦合。对这些反应的深入系统探索将有助于加深对配位反应和有机反应本质的认识，从而为新型功能化配合物的设计合成组装提供新的思路和方向。
结论摘要：
英文主题词polyoxometalate; bi-functional catalyst; solvothermal in situ reaction; C-C bond formation; pyridine
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期刊论文
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Synthesis and Crystal Structure of Substituted Tetramethylcyclopentadienyl Dimolybdenum Metal Carbon
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Self-Process-Programmed Structural Diversity in Supramolecular Assembly Based on Polyoxometalate Ani
Synthesis, structure and property of a new inorganic-organic hybrid compound [Cu(phen)(2)][Cu(phen)H
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