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Preparation of basic magnesium carbonate and its thermal decomposition kinetics in air
  • ISSN号:1009-606X
  • 期刊名称:《过程工程学报》
  • 时间:0
  • 分类:O614.121[理学—无机化学;理学—化学] TQ132.2[化学工程—无机化工]
  • 作者机构:[1]Civil and Environmental Engineering School, University of Science and Technology Beijing, Beijing 100083, China, [2]National Key State Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
  • 相关基金:Project(20876160) supported by the National Natural Science Foundation of China
中文摘要:

基本的镁碳酸盐的热分解过程被调查。第一,基本的镁碳酸盐从菱镁矿被准备,并且产品的特征被 X 光检查衍射(XRD ) 和扫描电子显微镜学(SEM ) 检测。随后,在空中的基本的镁碳酸盐的热分解过程被 thermogravimetry 微分的 thermogravimetry (TG-DTG ) 学习。XRD 的结果证实基本的镁碳酸盐的化学作文是 4MgCO3 杮??????????????? 灧吗??

英文摘要:

The thermal decomposition process of basic magnesium carbonate was investigated. Firstly, Basic magnesium carbonate was prepared from magnesite, and the characteristics of the product were detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Subsequently, the thermal decomposition process of basic magnesium carbonate in air was studied by thermogravimetry-differential thermogravimetry (TG-DTG). The results of XRD confirm that the chemical composition of basic magnesium carbonate is 4MgCO3·Mg(OH)2·4H2O. And the SEM images show that the sample is in sheet structure, with a diameter of 0.1-1 μm. The TG-DTG results demonstrate that there are two steps in the thermal decomposition process of basic magnesium carbonate. The apparent activation energies (E) were calculated by Flyrm-Wall-Ozawa method. It is obtained from Coats-Redfem's equation and Malek method that the mechanism functions of the two decomposition stages are D3 and A1.5, respectively. And then, the kinetic equations of the two steps were deduced as well.

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期刊信息
  • 《过程工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院过程工程研究所
  • 主编:张锁江
  • 地址:北京市海淀区中关村北二街1号过程大厦
  • 邮编:100190
  • 邮箱:CJPE@HOME.IPE.AC.CN GCGC@HOME.IPE.AC.CN
  • 电话:010-62554658
  • 国际标准刊号:ISSN:1009-606X
  • 国内统一刊号:ISSN:11-4541/TQ
  • 邮发代号:80-297
  • 获奖情况:
  • 国家中文核心期刊,中国科学院核心期刊,中国期刊方阵“双效”期刊,中国科学院优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:11515