采用表面机械研磨处理(Surface Mechanical Attrition Treatment,SMAT)技术实现了Cu-10%Ni的表面纳米化。采用X射线衍射仪(XRD)、场发射扫描电镜(SEM)、能量色散谱(EDS)等研究了表面纳米化Cu-10%Ni合金在酸性硫酸钠溶液(0.05 mol/L Na2SO4+0.05 mol/L H2SO4)的电化学腐蚀行为。结果表明:原始Cu-10%Ni合金和表面纳米化合金在腐蚀介质中的极化曲线均有钝化现象产生;但表面纳米化处理之后的合金的耐蚀性下降了,腐蚀速率加快了;且合金的腐蚀性能随着表面纳米化时间的延长逐渐降低。
By means of surface mechanical attrition treatment (SMAT),a nanostructured surface layer was formed on Cu-lOwt% Ni plate.XRD (X-ray diffraction), SEM (scanning electron microscope ), EDS (energy -dispersive spectroscopy)technique were used to experimentally investigate the electrochemical corrosion behavior of surface nanocrystallization Cu-10wt%Ni alloy in acid sodium sulfate solution (0.05 mol/L Na2SO4 + 0.05 mol/L H2SO4).The experiment results showed that the Cu-lOwt%Ni alloy with surface nanometer crystallization had lower corrosive resistance than the coarse Cu-10wt%Ni alloy.And the corrosion rate became faster than the original coarse sample.As the treatment time prolonged, the corrosion property of the Cu-10wt%Ni alloy decreased gradually.