以不同的多极量子数和初态,我们用约化的线性熵研究CH(CH3)3的耦合CH伸缩和弯曲振动的动力学纠缠,结果表明:在多极量子数大于等于3时,态|0,2N)的最大纠缠能在较短的时间内得到;态|N,0)的纠缠振荡频率比态|0,2N)的要小,而振荡的幅度要大.
The dynamical entanglement for the coupled C-H stretch and bend vibrations in CH(CF3)3 is studied in terms of the reduced linear entropy for various polyads N and initial states. It is shown that for a given polyad N≥3, a maximum entanglement for state |0,2N) can be obtained with a shorter time, and the entanglement oscillatory frequency for state |N,0) is shorter than that for state |0,2N), where the amplitude of the former state is larger than that of the later one.