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七种植物籽油中脂肪酸成分的比较分析(英文)
  • ISSN号:1001-6880
  • 期刊名称:天然产物研究与开发
  • 时间:0
  • 页码:69-75+93
  • 分类:O657[理学—分析化学;理学—化学]
  • 作者机构:[1]长沙学院生物与环境工程系,长沙410022
  • 相关基金:国家自然科学基金(81173533); 湖南省教育厅重点项目(11A017)
  • 相关项目:基于药物代谢组学方法研究茵陈蒿汤抗肝纤维化的药效物质基础及作用机理
中文摘要:

为全面评价生姜质量,通过GC-MS和HPLC法分别对不同产地生姜样品中挥发油和姜辣素进行比较分析。结果从9种生姜挥发油中分别鉴定了24~28种化学成分,占挥发油总量的85.31%~93.67%,主要为β-水芹烯(9.96%~20.15%)、莰烯(3.54%~14.53%)、柠檬醛(6.52%~12.49%)、β-柠檬醛(3.96%~7.44%)、姜烯(13.81%~19.74%)、姜黄烯(tr~5.52%)、β-倍半水芹烯(5.08%~6.22%)和β-红没药烯(2.63%~3.34%)等单萜和倍半萜类活性成分。9种生姜样品中6-姜辣素含量在0.067%~0.391%之间,均达到了现行中国药典不低于0.05%的规定。可见不同产地生姜主要活性成分含量差异较大。故以生姜的主要特征性有效成分姜烯、姜黄烯与6-姜酚共同作为其质量评价指标,将更加科学合理。

英文摘要:

In order to evaluate the quality of ginger more comprehensively,comparative analysis of the main active constituents of ginger samples collected from different origins were performed by GC-MS and HPLC methods proposed in this work. The ginger volatile oils were extracted by water distillation method and analyzed by GC-MS. Then the chemical constituents were identified by searching NIST02 MS database and semi-quantified by peak area normalization method.Gingerols were extracted by methanol and then determined by HPLC method. The obtained results showed that 24 to 28 compounds in the volatile oils of 9 ginger samples were identified by GC-MS,which accounted for 85. 31% to 93. 67%of total essential oils,respectively. β-Phellandrene( 9. 96% ~ 20. 15%),camphene( 3. 54% ~ 14. 53%),citral( 6. 52% ~ 12. 49%),β-citral( 3. 96% ~ 7. 44%),zingiberene( 13. 81% ~ 19. 74%),curcumene( tr ~ 5. 52%),β-sesquiphellandrene( 5. 08% ~ 6. 22%) and β-bisabolene( 2. 63% ~ 3. 34%) were the eight main active constituents.As for non-volatile components,the contents of 6-gingerol in the 9 ginger samples were in the range of 0. 067% to0. 391%,respectively,higher than 0. 05% specified in the current Chinese pharmacopeia. But there existed obvious differences in main active constituents and their amounts among the 9 ginger samples. Thus,to specify three characteristic effective components including zingiberene,curcumene and 6-gingerol instead of one constituent 6-gingerol as the quality evaluation compounds of ginger should be much more comprehensive.

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期刊信息
  • 《天然产物研究与开发》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院成都文献情报中心
  • 主编:方曙(执行)
  • 地址:成都市一环路南二段16号
  • 邮编:610041
  • 邮箱:trcw@clas.ac.cn
  • 电话:028-85210304
  • 国际标准刊号:ISSN:1001-6880
  • 国内统一刊号:ISSN:51-1335/Q
  • 邮发代号:62-107
  • 获奖情况:
  • 1996年被评为四川省首界优秀期刊,2000年被评为四川省第二界优秀期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:29369