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中文摘要：
本文合成了一个二价钴配合物[CoL2^5（NCS）2],（配体L^5=4-对溴苯基-3,5-二（2-吡啶基）-1,2,4-三氮唑）。其结构由单晶X衍射结构分析,红外和电喷雾离子质谱表征。该配合物晶体属于三斜晶系,空间群为P↑-1,钴原子和2个三芳基三氮唑配体的4个氮原子（平面）和2个硫氰根的氮原子（轴向）配位形成扭曲的八面体构型。磁性测定表明在1.8～300K的温度范围内该配合物处于高自旋态。
英文摘要：
A new cobalt（Ⅱ） complex, [CoL2^5（NCS）2], [L^5=4-（ p-bromophenyl）-3,5-bis（2-pyridyl）-1,2,4-triazole], was synthesized and its structure was determined by single crystal X-ray diffraction, FTIR and ESI-MS spectroscopy. The complex crystallizes in triclinic system with space group P↑-1. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. Magnetic measurements show that the complex is in a high-spin state in the 1.8～300 K range.
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