采用固相研磨法合成了铕(Ⅲ)-乙酰丙酮配合物,对掺杂聚乙二醇-聚丙烯酸共聚物与铕(Ⅲ)-乙酰丙酮配合物的相互作用及荧光强度的变化进行了对比研究;实验结果表明,掺杂聚乙二醇-聚丙烯酸共聚物的铕(Ⅲ)-乙酰丙酮配合物其荧光强度有了显著地提高。
Eu(Ⅲ)-acetylacetonate complex was prepared by grinding inorganic europium salts and acetylacetone at room temperature. Solid bases were used to promote the reaction. Fluorescence enhancement of Eu(Ⅲ)-acetylacetonate complex doped with block copolymer of PEO113-b-PAA82 was studied. Fluorescence spectroscopy showed that PEO113-b-PAA82 is a fluorescence enhancement system. We discussed the relation of the constitution of complexes and the luminescence.