中文摘要：

制备了基于淀粉三（4-三氟甲氧基苯基氨基甲酸酯）衍生物的涂敷型手性固定相（CSP1），并考察了其手性识别能力。研究表明：与商品化ChiralpakAD柱相比，CSP1显示出较低的手性识别能力；CSPI的手性识别能力随流动相中异丙醇含量的降低而升高；与以乙醇为流动相添加剂相比，使用异丙醇为添加剂更有利于对映体的分离。此研究拓展了多糖类衍生物手性固定相的种类。

英文摘要：

A coated-type chiral stationary phase （CSPI） based on amylose tris （4-trifluoromcthoxyphenylcarbamate） was prepared and evaluated for HPLC enantioseparations. Studies revealed that the prepared CSP exhibited lower chiral recognition compared to a widely-used, commercially available column, Chiralpak AD. With less 2-propanol added in the mobile phases, better resolutions were obtained on CSPI. Additionally, when ethanol was used instead of 2-propanol as mobile phase additive, poorer enantioseparations were achieved. This work provides a new polysaccharide-based CSP for HPLC enantioseparation.