位置:成果数据库 > 期刊 > 期刊详情页
pH值对红壤和黄土中铊的吸附-解吸特征的影响
  • ISSN号:1003-6504
  • 期刊名称:环境科学与技术
  • 时间:0
  • 页码:-
  • 分类:X53[环境科学与工程—环境工程]
  • 作者机构:[1]广州大学化学化工学院,广州大学分析测试中心,广东广州510006, [2]广州大学环境科学与工程学院,广东广州510006, [3]环境保护部华南环境科学研究所,广东广州510655
  • 相关基金:国家自然科学青年基金项目(40903044);国家自然科学青年基金项目(41203061);广州大学人才引进科研启动项目
  • 相关项目:采矿区土壤对铊的吸附/解吸特性及影响因素研究-野外监测与实验室模拟
作者: 李祥平|
中文摘要:

研究了不同pH条件下红壤和黄土对毒害重金属铊的等温吸附一解吸行为,结果表明,T1+在红壤和黄土中的吸附量均受pH值影响明显。红壤中,在pH=2时吸附量最小,吸附率为3%,吸附量和吸附率随着pH的升高而增加,在pH=10时,吸附量为89.93mg/kg,吸附率为61.3%;黄土中,pH从4增加到6时,吸附率增加明显,从14%骤升至71.2%,pH=10时,最大吸附量为139.67mg/kg,吸附率最大为83.8‰红壤和黄土的吸附都符合Langmuir和Ternkin方程。解吸过程中,pH=2时,红壤和黄土的解吸率最高,并且解吸率随着初始浓度的增加而增大,最大分别达到78.696和85.2%,同等条件下,黄土的解吸率高于红壤;在pH=4-10,红壤的解吸有一定的滞后现象,而黄土解吸量随吸附量的增加近似线性增加,无明显滞后现象。

英文摘要:

The isotherm adsorption and desorption behaviors of thallium in red soil and loess under different pH were studied. Results indicated that the adsorption amount of T1+ in two soils was significantly affected by pH. In red soil, the adsorption amount of T1+ was the least of 3% at pH 2, and adsorption amount and adsorption rate were increased with increasing pH. The adsorption amount and adsorption rate were 89.93 mg/kg and 61.3% at pH 10 respectively. In loess, the adsorption rate increased obviously with increasing pH from 4 to 6, and upsurged from 14% to 71.2%. The .maximum absorbance and adsorption rate were 139.67 mg/kg and 83.8% respectively at pH 10. The adsorption of T1+ in two soils could be described by Langmuir and Temkin isotherm equation satisfactorily. The desorption rate of T1+ was the most at pH 2 in two soils, and it increased with increasing initial concentration of T1+ up to the maximum of 78.6% and 85.2% respectively. The desorption rate of T1 + in loess was higher than that in red soil at the same condition. The desorption of T1+ in red soil exhibited hysteresis at pH 4-10, but in loess without obvious hysteresis, the amount of adsorption and desorption were approximate linear.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《环境科学与技术》
  • 中国科技核心期刊
  • 主管单位:湖北省环境保护厅
  • 主办单位:湖北省环境科学研究院
  • 主编:袁道先
  • 地址:武汉市武昌珞珈山八一路338号
  • 邮编:430072
  • 邮箱:hjkxyjs@yahoo.com.cn
  • 电话:027-87643502 87643503
  • 国际标准刊号:ISSN:1003-6504
  • 国内统一刊号:ISSN:42-1245/X
  • 邮发代号:38-86
  • 获奖情况:
  • 中文核心期刊,第三界国家期刊奖湖北省科技期刊参评提名奖,全国环境期刊一等奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:37319