研究了土壤有机质对Tl+在红壤和黄土2种土壤中的吸附-解吸行为的影响。结果表明,去除土壤有机质后红壤和黄土对Tl+的吸附量均明显下降,下降幅度最高分别达到24.7%和28.2%,黄土的下降幅度大于红壤;黄土对Tl+吸附率最高下降幅度约为20%,也高于红壤的15%。土壤有机质对Tl+吸附的贡献率平均值分别是黄土39.2%、红壤32.8%。2种土壤对Tl+的解吸量在去除有机质之后都明显增大,在初始Tl+浓度较高的情况下,增大幅度明显;并且Tl+的初始浓度越高,土壤在去有机质前后的解吸率相差就越大,在Tl+最大处理浓度为20 mg/L时,红壤和黄土的解吸率增加分别达到60.8%和65.5%。
The effects of present organic matter in red soil and loess on the Tl+ adsorption-desorption behaviors were investigated.The results showed that the adsorption of Tl+ by both red soil and loess was remarkabley decreased after the removal of soil organic matter(SOM).The reduce in Tl+ adsorption capacity varied with different initial Tl+ concentrations,and the greatest degree was 24.7% and 28.2% for red soil and loess,respectively.The greatest decrease degree in Tl+ adsorption rate by loess was about 20%,which was higher than that by red soil.The contribution of SOM to the Tl+ adsorption by loess and red soil was 39.2% and 32.8%,respectively.In addition,the desorption of Tl+ from both loess and red soil was enhanced after the removal of SOM,particularly for high initial Tl+ concentration.When the initial Tl+ concentration was 20 mg/L,the desorption rate increased to 60.8% and 65.5% for red soil and loess,respectively.