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Ternary System of Fe-based Ionic Liquid, Ethanol and Water for Wet Flue Gas Desulfurization
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:TQ546.5[化学工程—煤化学工程] X701.3[环境科学与工程—环境工程]
  • 作者机构:[1]Research Group of Environmental Catalysis and Separation Process, College of Chemical Engineering,Beijing University of Chemical Technology, Beijing 100029, China
  • 相关基金:Supported by the National Natural Science Foundation of China (21076019, 90610007), the National High Technology Research and Development Program of China (2007AA06Z115), the Ph.D. Programs Foundation of Ministry of Education of China (20090010110003 ), the Fundamental Research Funds for the Central Universities (ZD 1001).
中文摘要:

基于 Fe 的离子的液体(Fe-IL ) 被混合 FeCl3 综合 ? 走吗??

英文摘要:

Fe-based ionic liquid (Fe-IL) was synthesized by mixing FeCl3·6H2O and 1-butyl-3-methylimidazolium chloride [Bmim]C1 in this paper. The phase diagram of a ternary Fe-IL, ethanol and water system was investigated to construct a ternary desulfurization solution for wet flue gas desulfurization. The effects of flow rate and concentration of SO2, reaction temperature, pH and Fe-IL fraction in aqueous desulfurization solution on the desulfiariza- tion efficiency were investigated. The results shows that the best composition of ternary desulfurization solution of Fe-IL, ethanol and water is 1 : 1.5 : 3 by volume ratio, and pH should be controlled at 2.0. Under such conditions, a desulfurization rate greater than 90% could be obtained. The product of sulfuric acid had inhibition effect on the wet desulfurization process. With applying this new ternary desulfurization solution, not only the catalyst Fe-IL can be recycled and reused, but also the product sulfuric acid can be separated directly from the ternary desulfurization system.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
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  • 被引量:385