中文摘要：

以2-（二苯基膦）乙基三乙氧基硅烷和正硅酸乙酯为混合硅源，运用延时共缩聚法制备带有二苯基膦（PPh2-）修饰配体的KIT-6型介孔氧化硅材料，通过络合Ru（Ⅱ）获得固载化Ru（Ⅱ）有机金属催化剂（Ru-PPh2-KIT-6），该催化剂具有规整介孔结构．在水相烯丙醇异构化反应中显示高活性和高选择性，催化性能接近均相催化剂，活性相与载体结合牢固，能够重复使用5次以上．

英文摘要：

A diphenylphosphine（ PPh2 ）-modified KIT-6 type mesoporous silica was synthesized by co-condensation method using tetraethoxysilane（TEOS） and 2-（diphenylphosphino） ethyltriethoxysilane （DPPTS） as the mixed silicon source, from which the immobilize Ru（Ⅱ） organometallic catalyst was obtained through strong coordination between the PPh2-group on the KIT-6 support and the Ru（Ⅱ）. The as-prepared Ru-PPh2-KIT-6 catalyst exhibited ordered mesoporous structure. During the isomerization of homoallylic alcohol in an aqueous medium, the Ru-PPh2- KIT-6 catalyst exhibited high activity and selectivity, almost the same as the corresponding homogeneous catalyst. The catalyst could be used repetitively for more than 5 times owing to the strong interaction of the Ru（Ⅱ） active sites with the support which prevent them from leaching.