首次报道了基于全共轭高分子材料聚苯撑苯并二恶唑(PBO)作为空穴传导材料及电子给体,富勒烯(C60)作为电子传输层及电子受体的双层异质结器件.研究发现:该结构器件具有明显的光伏响应特征,开路电压达0.76V,短路电流0.07mA/cm^2;而且在正向偏压下,器件还表现出了较强的激基复合物电致发光现象,在7.1V偏压下,器件的亮度达5.3×10^3cd/m^2,而器件的最高发光效率可达1.8cd/A.该研究表明,基于PBO/C60双层异质结的多功能光电器件具有较好的开发价值和应用前景.
In this work, a bilayer device, which used a fully conjugated polymer poly( p-phenylene ben- zobisoxazole) (PBO) as a hole transporting material and buckminsterfullerene (C60) as an electron transporting material, was fabricated. It was found that, the device showed both photovoltaic and electroluminesence characteristics. An open-circuit voltage of 0.76 V and an short-circuit current of 0.07 mA/cm^2 were obtained, and meanwhile a yellow exciplex emitting with a maximum brightness of 5.3 × 10^3 cd/m^2 was also observed from the same device. Our work suggests the structure of PBO/C60 can be used to develop a multifunction device.