采用紫外可见分光技术研究了磁性瓜环(MQ[n])对水体污染物腐殖酸(HA)的去除性能、稳定性及磁性能.考察了MQ[n]的投加量、HA的初始浓度、溶液温度、作用时间及pH值等因素对去除HA的影响.结果表明,MQ[n]对HA具有很好的去除作用,其中,MQ[n]投加量与pH值对HA的去除效果影响较大.其较优条件为MQ[n]投加量20 mg、HA初始质量浓度10 mg/L、吸附温度315 K、平衡时间360 min、pH值7.0,在此条件下,MQ[n]对HA的去除率达到98.73%.MQ[n]稳定性好,且易于磁性分离.
The removal capacity of magnetic cucurbiturils(MQ[n]) on humic acid(HA),stability and magnetic properties were studied using uv-visible spectrophotometer technology.The influence of environment factors for removal of HA,such as the dosage of MQ[n],the initial concentration of HA solution,temperature,time,and the pH of aqueous solution on removal of HA were investigated.The results show that MQ[n] has good removal effect for HA and the dosage of MQ[n] and the pH of aqueous solution were found to be the key influential factors.It was found that a relatively large removal (98.73%) was attained from a solution at an optimized MQ[n] dosage of 20 mg,the initial concentration of HA solution 10.00 mg/L,temperature 315 K,reaction time 360 min and pH 7.0.Meanwhile,MQ[n] has good stability and can be separated from wastewater easily.