硫酸盐离子修改了钇铝柘榴石: Ce 3+ 黄磷被一起沉淀方法准备并且由 X 光检查衍射,传播电子显微镜学,和光致发光描绘了。光致发光(PL ) 上的硫酸盐离子的效果同样准备的钇铝柘榴石的性质: Ce 3+ 黄磷被学习,与钠 dodecyl,硫酸盐(SDS ) 正在被加到 R 3+(Ce 3+, Y 3+, 艾尔 3+) 离子。结果显示了那纯钇铝柘榴石: 有硫酸盐离子的不同比率的 Ce 3+ 黄磷能被在 950 点锻烧同样综合的先锋容易获得 ? ??? 猯灵 ????? ‰吗??
The sulfate ions modified YAG:Ce~(3+) phosphors were prepared by co-precipitation method and characterized by X-ray diffraction,transmission electron microscopy,and photoluminescence.Effects of sulfate ions on the photoluminescence(PL) property of the as-prepared YAG:Ce~(3+) phosphors were studied,with sodium dodecyl sulfate(SDS) being added to R~(3+)(Ce~(3+),Y~(3+),Al~(3+)) ions.Results indicated that pure YAG:Ce~(3+) phosphors with different ratios of sulfate ions could be easily obtained by calcining the as-synthesized precursor at 950 ℃ for 2 h,the YAG:Ce~(3+) phosphors with an optimal mass ratio of 3.5 wt.%SDS had the highest emission intensity and the best dispersion behavior,and the fluorescence decay of the as-obtained YAG:Ce~(3+) phosphors was related to the lattice defect,reabsorption and cross correlation.Furthermore,thermal quenching properties of the YAG:Ce~(3+) phosphors and the YAG:Ce~(3+) phosphors with 3.5 wt.%SDS were also discussed,indicating that the YAG:Ce~(3+) with SDS phosphors could have potential applications in the daylight LEDs or warm white LEDs.