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溶剂对电纺聚酯纳米纤维可纺性的影响
  • 期刊名称:合成纤维工业. 2007,Vol. 30, No. 2, 11-13
  • 时间:0
  • 分类:TQ342.2[化学工程—化纤工业]
  • 作者机构:[1]北京服装学院材料工程学院,北京100029, [2]北京市服装材料研究开发与评价重点实验室,北京100029
  • 相关基金:国家教育部新世纪优秀人才支持计划资助(NCET-05-0204);国家自然科学基金项目(50503001);北京市自然科学基金项目北京市教委科技发展计划重点项目(KZ200510012010);北京市优秀人才培养资助(20051D0500101).
  • 相关项目:基于富勒烯的一维连续纳米纤维与有序阵列的电纺制备及研究
中文摘要:

利用静电纺丝法制备聚酯(PET)纳米纤维,选择苯酚和四氯乙烷,三氟乙酸,三氟乙酸和二氯甲烷3种溶剂分别溶解PET切片进行静电纺丝,通过扫描电子显微镜(SEM)对纤维表面形态进行观察,结果表明:三氟乙酸和二氯甲烷混合溶剂溶解PET制备的电纺纤维较好。使用视频光学接触角测定仪测试PET电纺纤维膜与其流延膜的接触角,通过分析两者表面结构,证明PFT电纺纤维膜能产生较强的疏水功能。

英文摘要:

Polyester nanofiber can be prepared by electrospinning process from PET chips separately dissolving in three kinds of solvents, namely, the mixture solvent of phenol and tetrachloroethane, trifluoroacetic acid and the mixture solvent of trifluoroacetic acid and dichlormethane. The surface morphology of the obtained fiber was studied by scanning electron microscopy. The results showed that the mixture of trifluoroacetic acid and dichlormethane was satisfying in electrospun fiber production. The contact angles of electrospun PET fiber film and cast film were measured by video optical contact angle measurement. The surface structure of these two films was analyzed, which indicated that the PET electrospun fiber film had higher hydrophobicity.

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