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Extinction efficiencies of mixed aerosols measured by aerosol cavity ring down spectrometry
  • ISSN号:1001-6538
  • 期刊名称:Chinese Science Bulletin
  • 时间:2012.7.7
  • 页码:2567-2573
  • 分类:TQ013.1[化学工程] X513[环境科学与工程—环境工程]
  • 作者机构:[1]State Key Laboratory for Structural Chemistry of Unstable and Stable Species,Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China, [2]Beijing National Laboratory for Molecular Science,State Key Laboratory for Structural Chemistry of Unstable and Stable Species,Peking University,Beijing 100871,China
  • 相关基金:supported by the Knowledge Innovation Program of the Chinese Academy of Sciences(KJCX2-EW-H01,KJCX2-YW-N24);the National Basic Research Program of China(2011CB403401);the National Natural Science Foundation of China(40925016,40830101,21077109,41005070)
  • 相关项目:含氧挥发性有机物(OVOCS)的大气化学过程研究
中文摘要:

在光谱学仪器下面的一枚洞戒指为在这份报纸测量纯、混合的喷雾器的扑灭效率被介绍并且设计。通过平均 500 单个波形, 8.4 的最小的可检测的喷雾器扑灭系数

英文摘要:

A cavity ring down spectroscopy instrument was introduced and designed for measuring extinction efficiencies of pure and mixing aerosols in this paper.Through averaging 500 individual waveforms,the minimal detectable aerosol extinction coefficient of 8.4 × 10-7 m-1 was achieved.By the test results using the NaCl particles,we concluded that this system could measure the extinction efficiencies of an aerosol with an uncertainty less than 3% under laboratory controlled experimental conditions.The refractive indices of different aerosols were retrieved through comparing the measured extinction efficiencies of each aerosol type with which predicted by Mie theory.Aerosols composed of ammonium sulphate and succinic acid with different weight ratios were used to create a model of mixed aerosols using these two materials,whose extinction efficiencies and complex refractive indices were derived.The refractive indices of the mixed aerosols were also calculated by various optical mixing rules.We found that all the molar refraction/absorption mixing rule,the volume ratio linear rule,and Maxwell-Garnett rule did provide comparable results,of which the volume ratio linear rule gave a slightly worse fit than the others.

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