Significant effects of branches and bromine substitution of near-infrared two-photon photosensitizers on the generation of singlet oxygen
- ISSN号:1000-6818
- 期刊名称:《物理化学学报》
- 时间:0
- 分类:O437[机械工程—光学工程;理学—光学;理学—物理] O613.3[理学—无机化学;理学—化学]
- 作者机构:[1]College Of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
- 相关基金:This work was supported by the National Natural Science Foundation of China (20776165, 20702065, 20872184), the Fundamental Research Funds,for the Central Universities (CDJZR10220006) and Chongqing Natu- ral Science Foundations (CSTC2012jjB50007). Fang Gao appreciates warm encouragements from the Program of New Century Excellent Talents in University (NCET-10-0876). We thank Key Laboratory of Photochemi- cal Conversion and Optoelectronic Materials, Techinical Institute of Phys- ics and Chemistry, Chinese Academy of Sciences for laser detection.
关键词:
双光子吸收, 单线态氧, 光敏剂, 溴原子, 近红外, 分支机构, 光物理性质, 光学, two-photon absorption, singlet oxygen, photosensitizers
中文摘要:
这封信在一个光子和汗衫氧的二光子的吸收产生上报导分支的影响和 photosensitizers 的溴替换。在红外线附近的 femtosecond Ti:squassier 激光被利用决定在 20 nm 的间隔从 700 ~ 880 nm 调节波长的 photosensitizers 的二光子的性质。一个光子并且二光子光并且 photosensitizers 的 photophysical 性质在分支和代替的溴原子上显示出重要依赖。
英文摘要:
This letter reports the influence of branches and bromine substitution of the photosensitizers on one- and two-photon absorption generation of singlet oxygen. Near-infrared femtosecond Ti:squassier laser was utilized to determine two-photon properties of the photosensitizers tuning wavelength from 700 to 880 nm at intervals of 20 nm. One- and two-photon optical and photophysical properties of the photosensitizers show significant dependence on the branches and substituted bromine atoms.