枝状分子因具有独特的化学结构,其光化学与光物理研究引起人们的关注。本文重点介绍了近二十年来报道的具有光诱导分子内能量转移的枝状分子的化学结构特点,分析了不同因素对光诱导枝状分子内能量转移效率的影响;阐述了可以根据能量给体与受体的性质,对枝状体的分子内光诱导能量转移进行调控;概括了具有光诱导分子内能量转移性质的枝状分子的目前应用领域;总结了枝状体分子内能量转移面临的关键科学问题,并展望了具有光诱导分子内能量转移的枝状分子的发展方向。
Dendrimers possess great potentials in molecular devices due to their special chemical structures, which stimulates photochemical and photophyscial investigation of dendrimers. This paper describes the chemical structure characteristics of reported dendrimers with photoinduced intramolecular energy transfer nature in recent two decades,and presents the effects of various factors on photoinduced intramolecular energy transfer efficiency of dendrimers. This review also shows how to tune photoinduced intramolecular energy transfer efficiency based on the properties of energy-donor and acceptor. The application of photoinduced intramolecular energy transfer efficiency in dendrimers is generalized. The key scientific problems in the photoinduced intramolecular energy transfer efficiency in dendrimers are summarized. The development prospects of photoinduced intramolecular energy transfer in dendrimers is discussed.