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V2O5/WO3/TiO2催化剂制备及其SCR性能研究
  • 期刊名称:吕刚,宋崇林,高文斌,龚彩荣,裴毅强,V2O5/WO3/TiO2催化剂制备及其SCR性能研究,工程热
  • 时间:0
  • 分类:TK421.5[动力工程及工程热物理—动力机械及工程]
  • 作者机构:[1]天津大学内燃机燃烧学国家重点实验室,天津300072, [2]天津大学材料科学与工程学院,天津300072
  • 相关基金:国家自然科学基金资助项目(No.50506020);霍英东基金青年教师优选资助课题(No.114027);天津市应用基础及前沿技术研究计划重点项目(No.08JCZDJC20000);国家“863”计划资助项目(No.2006AA110112)
  • 相关项目:柴油机排气中氮氧化物选择性催化还原反应的基础研究
中文摘要:

本文通过浸渍法制备了V2O5/TiO2系列筛选催化剂及V2O5/WO3/TiO2负载型催化剂,并在模拟评价装置上考察了上述催化剂在SCR反应中的催化性能。结果表明,V2O5在涂层材料中应该低于3wt.%;钒系催化剂对NOx的净化效率随反应温度的升高,先增加而后减小,存在一个适宜反应温度窗口;随反应温度升高,NH3泄漏量逐渐降低,在温度达到350℃之后,NH3泄漏量不再随温度的升高而变化;SCR反应温度较低时HC和CO浓度基本不变,但从450℃开始,HC浓度逐渐降低,而CO浓度则急剧升高;随NOx/NH3比例增加,NOx转化效率逐渐降低.

英文摘要:

Titania-supported tungsten and vanadium oxides with different WO3 and V2O5 loadings have been prepared by the impregnation method. Their activity and performance in the selective catalytic reduction (SCR) in NOx with NH3 are also characterized by a simulated evaluating rig. The results show that the content of V2O5 should be less than 3 wt.% of the entire coating. The conversion efficiency of NOx in SCR reaction is increased with the temperature until the critical temperature is reached, and then decreased with temperature. Therefore, there is a best temperature-window for NH3-SCR reaction. As to NH3,with the temperature increasing, leaking of NH3 gradually reduced incipiently and then kept as a constant after the temperature reaches 350℃. The concentration of HC and CO at the lower reactive temperature are invariable, however, as the temperature reached 450℃, the concentration of HC reduced gently and that of CO increased sharply. In addition, reduction activity of NOx is gradually reduced as the proportion of NOx to NH3 is enhanced.

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