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掺杂Al_2O_3的CuO/CeO_2催化剂催化富H_2气体中CO的优先氧化反应
  • 分类:O643.32[理学—物理化学;理学—化学]
  • 作者机构:[1]内蒙古工业大学化工学院,内蒙古呼和浩特010051
  • 相关基金:国家自然科学基金(项目编号20963005); 内蒙古自然科学基金(项目编号200607010204)联合资助
中文摘要:

采用共沉淀-浸渍法制备了系列催化剂12%CuO/CeO2-Al2O3,将该系列催化剂用于富H2中CO的优先氧化反应。通过XRD、BET、TPR等技术对各催化剂样品的结构和性质进行了表征,考察了Al2O3的含量对CO选择氧化反应的影响。结果表明,添加70%Al2O3催化剂的CO优先氧化性能良好,氧化活性高低与Al2O3的含量有关。

英文摘要:

A series of 12wt% CuO/CeO2 -A1203wt% catalysts for preferential CO oxidation were prepared by co - precipitation method. The structures and properties of catalysts were characterized by X - ray diffraction patten, BET surface area measurements and TPR to investigate the influence of A1203 content on the CO selective oxidation reaction. The results showed that content of Al203 had a great impact on the catalytic property. It was found that 12wt% CuO/CeO2 -A120370% catalyst exhibited very good catalytic performance for the PROX reaction related to the Al2 O3 content.

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