通过水溶液聚合法合成了羽毛蛋白接枝丙烯酸-丙烯酰胺高吸水树脂,即FP-P(AA-AM)。研究了树脂在单一Cd2+溶液中的吸附行为以及在Cd2+、Cu2+、Zn2+三元混合溶液中的选择性吸附性能。结果表明,在单一Cd2+溶液中,FP-P(AA-AM)树脂对Cd2+的吸附容量随硫酸镉溶液浓度的增大而增大,最高可达2.4mmol/g。吸附Cd2+至饱和的树脂能在1mol/L的HCl溶液中很好的进行解吸附,3min时解吸附率即可达到83.3%。在较高浓度的三元金属离子混合溶液中,FP-P(AA-AM)树脂对3种离子呈现出一定的选择性吸附,其平衡吸附量顺序为:Cu2+〉Cd2+〉Zn2+。
Feather protein(FP) grafted poly(acrylic acid-acrylamide) superabsorbent polymers were prepared by aqueous solution polymerization.The adsorption behavior in the single Cd2+ solution and the selective adsorption in the ternary solution of Cd2+、Cu2+ and Zn2+ were discussed.The results showed that the amount of adsorption for Cd2+ in the single ion solution increased with the increasing metal ion concentration,and the maximum was found to be 2.4mmol/g.The absorbed copolymers for Cd2+ can desorb in 1mol/L HCl solution and the desorptive ratios reached a constant value,83.3%,after 3minutes desorption.The grafted copolymers showed selective adsorption in ternary metal ion solution,and the sequence of the adsorption uptakes was Cu2+Cd2+Zn2+.