目的合成新型的光致变色化合物.方法联茚满烯二酮类光致变色磁性化合物在晶体状态下光照变色,同时产生稳定的自由基.这些特殊的性质使得这一系列化合物具有巨大的潜在应用价值.连用格式试剂与酮加成的经典反应.结果合成了新的(联茚满)烯二酮类化合物即3,3’-二对乙氧基苯-基3,3’-二羟基-2,2’-二茚叉基-1,1’-二酮.结论红外、核磁、元素分析、晶体结构4种波谱手段能确定其结构.
Objective To synthesize new biindenylidene compound. Methods The biindenylidene derivatives are unusual in that they simultaneously generate radicals and undergo photochromism in the crystalline state. Results The preparation of a new series of 3, 3'-diaryl biindenylidenedione derivatives is made. Conclusion The new compound is carefully characterized by H-NMR, IR, elemental analysis and X-ray crystallography.