中文摘要：

用三苯基4-乙烯基苄基氯化季膦盐和三种芳醛的Wittig反应合成了具有二苯乙烯类侧链的三种苯乙烯衍生物：4-乙烯基二苯乙烯（VS）,4’-N,N-二甲氨1基-4-乙烯基二苯乙烯（DMAVS）和4-（2-（9-蒽基））-乙烯基苯乙烯（AVS）。这三种物质都具有良好的光致发光性能,随取代基的不同,光致发光光谱的最大发射位置从375到530nm,强度也随着共轭程度的加大和推电子基团的引入而大幅度增强。

英文摘要：

A series of styrene derivatives with stilbene-like pendant were synthesized through heterogeneous Wittig reaction of triphenyl-（4-vinyl）-benzylphosphornium chloride with aromatic aldehydes. The substituted styrenic monomer, 4-（2-aryl）-vinyl-styrene, was strongly photoluminescent in solution and in solid state. Introduced electron-pushing substituents and lengthened conjugation both enhanced the emission intensity and led to a red shift of emission bands, with the maximum emission wavelength shifted from 378 to 494 nm. The fluorescece quantum efficiencies were determined by employing quinine sulfate as reference; and 4-（2-anthryl）-vinyl-styrene （AVS） possessed the highest quantum efficiency（λ=494 nm, Фf=0.635）.