Ti-O Magnéli相氧化物因具有特殊的结构和性质自发现以来就备受关注。Ti-O Magnéli相氧化物优良的电子导电性、稳定性以及耐腐蚀性使得其在电化学领域应用广泛。综述了Ti-O Magnéli相氧化物的组成、结构、性质及其主要的制备方法,并总结归纳了该材料的主要应用。提供了Ti-O Magnéli相氧化物未来合成与应用研究的方向。
Ti-O Magnéli phase oxides are of great interest due to their high electronic conductivity,stability and anti-corrosion property. These properties lead to broad applications in the electrochemical,energy industry and many other fields. The compositions,structure and properties of Ti-O Magnéli phase oxides,as well as the synthesis methods and applications are summarized. Recently,there are intensive researches highlighting the wide applications of Ti-O Magnéli phase oxides in advanced energy systems. Some new ideas of synthesis and application of Ti-O Magnéli phase are also discussed.