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Application of upconversion luminescence in dye-sensitized solar cells
  • ISSN号:1001-6538
  • 期刊名称:Chinese Science Bulletin
  • 时间:0
  • 页码:96-101
  • 分类:TN244[电子电信—物理电子学] TM914.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, China, [2] The Key Laboratory for Functional Materials of Fujian Higher Education, China, [3] Institute of Material Physical Chemistry, Huaqiao University, Quanzhou 362021, China
  • 相关基金:This work was supported by the National High Technology Research and Development Program of China (2009AAO3Z217) and the National Natural Science Foundation of China (90922028, 50842027).
  • 相关项目:掺杂稀土转换发光晶态材料的可控制备及在染料敏化太阳能电池中的应用
中文摘要:

upconversion 光粉末 TiO2 :(Er3+ , Yb3+) 被一个热水的方法准备并且过去常制作敏化染料的太阳能电池(DSSC ) 。TiO2 :(Er3+ , Yb3+) 粉末经历 upconversion 光,变换染料不能与染料能吸收的 510700 nm 的波长吸收进可见的光的红外线的光,增加 DSSC 的光电流。TiO2 :(Er3+ , Yb3+) 也充当 p 类型掺杂物,提高氧化物电影的费密水平,它增加 DSSC 的 photovoltage。当 TiO2/luminescence 粉末的比率是在光层的 1/3 时, DSSC 的最好的表演被发现。在 100 mW 厘米的模仿的太阳的照耀下面 ? 2 (AM 1.5 ) ,包含 TiO2 的 DSSC :(Er3+ , Yb3+) 做为 undoped DSSC 与 6.41% 相比完成 7.28% 的 light-to-electricity 精力变换效率。

英文摘要:

An upconversion luminescence powder TiO2:(Er^3+, Yb^3+) is prepared by a hydrothermal method and used to fabricate dye-sensitized solar cell (DSSC). The TiO2:(Er^3+, Yb^3+) powder undergoes upconversion luminescence, converting infrared light which the dye can not absorb into visible light with wavelengths of 510-700 nm which the dye can absorb, increasing the photocurrent of the DSSC. TiO2:(Er^3+, Yb^3+) also acts as a p-type dopant, heightening the Fermi level of the oxide film, which increases the photovoltage of the DSSC. The best performance of the DSSC is found when the ratio of TiO2/luminescence powder is 1/3 in the luminescence layer. Under simulated solar irradiation of 100 mW cm^-2 (AM 1.5), the DSSC containing TiO2:(Er^3+, Yb^3+) doping achieves a light-to-electricity energy conversion efficiency of 7.28% compared with 6.41% for the undoped DSSC.

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