采用UV/TiO2、US—UV两种工艺分别降解饮用水中低浓度持久性有机氯农药(α-BHC,六六六),研究不同TiO2浓度条件下,紫外光催化降解α—BHC的降解效果,同时比较了不同粒径的TiO2对α—BHC降解效果的影响。分别考察了先紫外90min再超声30min与先超声30min再紫外光降解90min两种联用工艺对α—BHC去除效果。结果表明,TiO2粉末粒径越小,α—BHC去除率越高,先超声30min再UV光降解90min比先UV光降解90min再US空化30min的降解率高,说明超声对紫外有协同作用。
The two processes UV (ultraviolet)/TiO2 and US (ultrasound)/UV were used to degrade the trace persistent organic chlorine pesticide benzene hexachloride (α-BHC) , respectively. The UV photocatalytic degradation process of α-BHC was investigated for various initial TiO2 concentrations. Meanwhile the TiO2 of different size was used to elucidate the degradation efficiency of α-BHC. The effects of two operation conditions (UV 90 min before US 30 rain and US 30 min before UV 90 min) were also studied to compare the removal efficiency of α-BHC. The results showed that the removal percentage of α-BHC was gradually increasing with the decrease of Size of TiO2 particle, and the second operation process ( US 30 min before UV 90 min) was superior to the first operation process ( UV 90 rain before US 30 min), which suggested that US was synergy to UV process.