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Ortho-hydroxy assisted and copper-catalyzed oxidation of benzylic alcohol
  • ISSN号：1001-6538
  • 期刊名称：Chinese Science Bulletin
  • 时间：0
  • 页码：2817-2819
  • 分类：O643.36[理学—物理化学;理学—化学] TQ245.24[化学工程—有机化工]
  • 作者机构：[1]Hefei National Laboratory for Physical Science at Microscale, Joint-Lab of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
  • 相关基金：This paper is dedicated to Professor LIU YouCheng on the occasion of his 90th birthday. This work was supported by the National Natural Science Foundation of China （20628202 and 90813008）.
  • 相关项目：多孔超分子负载的纳米金属催化剂制备及其在有机反应中的应用
作者： Wan ChangFeng|Fan JinMin|Zhang JinTang|Wang ZhiYong|
关键词： 催化氧化, 铜催化剂, 邻羟基, 苄醇, 羰基化合物, 空气气氛, 配体, o-hydroxy, oxidation, o-hydroxyarylketones, copper catalysis
中文摘要：

为 o-hydroxyarylketones 的合成的一个有效、简单的协议被开发了。没有 ligands，反应在空气空气下面顺利继续铜催化剂的催化数量。这研究显示 o-hydroxy 在酒精的氧化起一个重要作用到相应羰基混合物。

英文摘要：

An efficient and simple protocol for the synthesis of o-hydroxyarylketones has been developed. The reaction proceeds smoothly with catalytic amounts of copper catalyst under air atmosphere without ligands. This study indicates that the o-hydroxy plays an important role in the oxidation of alcohol to the corresponding carbonyl compounds.

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