目的:研究水茄中化学成分。方法:利用硅胶、凝胶和反相等柱层析材料进行分离,通过ESI-MS和NMR波谱方法对分离得到化合物进行结构鉴定。结果:从水茄中分离得到9个化合物(1-9)。结构分别为neochlorogenin 6-O-β-D- qui-novopyranoside(1), neochlorogenin 6-O-β-D-xylopyranosyl-(1→3)-β-D-quinovopyranoside(2), neochlorogenin 6-O-α-L- rhamno-pyranosyl-(1→3)-β-D-quinovopyranoside(3),solagenin 6-O-β-D-quinovopyranoside(4),solagenin 6-O-α-L-rhamnopyranosyl-(1→3)-β-D-quinovopyranoside(5),异槲皮苷(6),芦丁(7),山柰酚(8)和槲皮素(9)。结论:所有化合物均首次从水茄中分离得到。
AIM:To investigate the chemical constituents of Solanum torvum Swartz.METHODS:The compounds were isolated by silica gel,Sephadex LH-20,and Rp-C18 column chromatography.Their structures were elucidated on the basis of spectral analysis of ESI-MS and NMR.RESULTS:Nine known compounds including neochlorogenin 6-O-β-D-quinovopyranoside (1),neochlorogenin 6-O-β-D-xylopyranosyl-(1→3)-β-D-quinovopyranoside (2),neochlorogenin 6-O-α-L-rhamnopyranosyl-(1→3)-β-D-quinovopyranoside (3),solagenin 6-O-β-D-quinovopyranoside (4),solagenin 6-O-α-L-rhamnopyranosyl-(1→3)-β-D-quinovopyranoside (5),isoquercetin (6),rutin (7),kaempferol (8) and quercetin (9) were isolated from S.torvum.CONCLUSION:All compounds were isolated from S.torvum for the first time.