用二-2-乙基己基磷酸(HDEHP)和P2O5混合物做萃取剂^241 Am^3+为示踪剂,做了从硝酸溶液中液-液萃取Am的实验研究。完成了硝酸浓度和震荡时间的变化影响^241 Am^3+萃取效率的条件实验。发现P20,的浓度≥0.0125mol/L时,^241 Am^3+ 的萃取效率大干98%;震荡时间≥30s,两相便可达到萃取平衡。分别用二乙撑三胺五乙酸(DTPA)-乳酸以及N%CO3溶液对^241 Am^3+进行反萃取。结果显示N%CO,溶液能给出很高的反萃效率。而且,在很短的震荡时间内,两相都能达到反萃平衡。
The solvent extraction of ^241Am^3 + from HNO3 solution has been completed by using a mixture of di-2- ethyl hexyl orthophosphpric aicd (HDEHP) and P2O5 as an extractant and ^241 Am^3+ as tracer. The condition experiments effecting of nitric acid concentration and period of equilibration on Am percent extractions were made. It has been found when the concentration of P2O5 is ≥0.0125 mol/L, the percent extraction of ^241Am^3+ is higher 98% and the equilibrium of the two phases can be achieved within the period of equilibration shorter than 30 s. ^241 Am^3 + was reextracted from the organic phases with diethylenetriamine pentacetic acid (DTPA) and lactic acid as well as Na2CO3 solutions, respectively. The results showed that quite high stripping efficiency for ^241Am^3 + can be given in Na2CO3 solutions. Moreover, the equilibrium of the two phases can be achieved within very short equilibrium time using the two kinds of stripping solutions.