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Preparation and Tribological Behavior of Hydrophobic Lanthanum Borate Nanosheets in Rapeseed Oil
  • ISSN号:1008-6234
  • 期刊名称:《中国炼油与石油化工:英文版》
  • 时间:0
  • 分类:TE62[石油与天然气工程—油气加工工程]
  • 作者机构:[1]Department of Oil Application and Management Engineering,Logistical Engineering University, Chongqing 401311, [2]Department of National Defense Architectural Planning and Environment Engineering,Logistical Engineering University, Chongqing 401311
  • 相关基金:the financial support of the National Natural Science Foundation of China(Project 50975282)
中文摘要:

Oleic acid-capped lanthanum borate (abbreviated as OA/LaBO3·H2O) nanosheets were prepared by the hydrothermal method. The microstructures of as-prepared OA/LaBO3·H2O were characterized by means of SEM, TEM,EDS, FTIR and XRD, respectively. Moreover, the friction and wear properties of OA/LaBO3·H2O as a lubricant additive in rapeseed oil were evaluated on a four-ball tribotester. The tribochemical characteristics of worn surfaces were investigated by SEM and XPS. The results showed that the hydrophobic OA/LaBO3·H2O nanosheets exhibited their morphology with a diameter in the range of 100 nm to 300 nm and a thickness of about 25 nm, and displayed excellent dispersing stability in rapeseed oil. In the meantime, the rapeseed oil doped with OA/LaBO3·H2O nanosheets markedly decreased the friction and wear of steel balls, and the optimal friction-reducing and antiwear ability of rapeseed oil was obtained at an OA/LaBO3·H2O content of 1.0%. The outstanding tribological performance of OA/LaBO3·H2O in rapeseed oil was attributed to the formation of a composite boundary lubrication film mainly composed of lubricious tribochemical species of B2O3, La2O3 and Fe2O3,and deposits of OA/LaBO3·H2O nanosheets as well as the adsorbates of rapeseed oil on rubbed surfaces.

英文摘要:

Oleic acid-capped lanthanum borate (abbreviated as OA/LaBO3·H2O) nanosheets were prepared by the hydrothermal method. The microstructures of as-prepared OA/LaBO3·H2O were characterized by means of SEM, TEM, EDS, FTIR and XRD, respectively. Moreover, the friction and wear properties of OA/LaBO3·H2O as a lubricant additive in rapeseed oil were evaluated on a four-ball tribotester. The tribochemical characteristics of worn surfaces were investigated by SEM and XPS. The results showed that the hydrophobic OA/LaBO3·H2O nanosheets exhibited their morphology with a diameter in the range of 100 nm to 300 nm and a thickness of about 25 nm, and displayed excellent dispersing stability in rapeseed oil. In the meantime, the rapeseed oil doped with OA/LaBO3·H2O nanosheets markedly decreased the friction and wear of steel balls, and the optimal friction-reducing and antiwear ability of rapeseed oil was obtained at an OA/LaBO3·H2O content of 1.0%. The outstanding tribological performance of OA/LaBO3·H2O in rapeseed oil was attributed to the formation of a composite boundary lubrication iflm mainly composed of lubricious tribochemical species of B2O3, La2O3 and Fe2O3, and deposits of OA/LaBO3·H2O nanosheets as well as the adsorbates of rapeseed oil on rubbed surfaces.

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期刊信息
  • 《中国炼油与石油化工:英文版》
  • 主管单位:中国石化集团公司
  • 主办单位:SINOPEC 石油加工研究所
  • 主编:汪燮卿
  • 地址:北京学院路18号
  • 邮编:100083
  • 邮箱:sylz@ripp-sinopec.com
  • 电话:010-82368292
  • 国际标准刊号:ISSN:1008-6234
  • 国内统一刊号:ISSN:11-4012/TE
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库)
  • 被引量:37