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PP-g-(GMA-co-St)增容PC/PP共混体系的形态与性能
  • 期刊名称:高分子材料科学与工程
  • 时间:0
  • 页码:55-58
  • 语言:中文
  • 分类:TQ314.245.9[化学工程—高聚物工业]
  • 作者机构:[1]四川大学高分子科学与工程学院,高分子材料工程国家重点实验室,四川成都610065
  • 相关基金:国家自然科学基金面上项目(20874066)
  • 相关项目:动态外场下PC/PE共混体系形态演变与调控
中文摘要:

运用分级注入方法制备了不同配比的PC/PP-g-(GMA-co-St)/PP共混物。通过力学性能测试、扫描电子显微镜观察、高压毛细管流变测试等方法考察了增容剂PP-g-(GMA-co-St)对PC/PP共混体系的形态与性能的影响。PP-g-(GMA-co-St)的加入提高了两相界面结合力,降低了分散相粒子尺寸,有效地改善了共混体系的相容性;同时PC/PP-g-(GMA-co-St)/PP体系的拉伸性能得到显著的提高,体系表观黏度提高,对剪切应力的敏感性降低。

英文摘要:

PP/PP-g-(GMA-co-St)/PC blends with different compositions were prepared by lateral-stage injection processing method,and the effects of polypropylene-g-(glycidyl methacrylate-co-styrene) (PP-g-(GMA-co-St)) compatiblizer on the morphology and properties of PC/PP blends were studied by mechanical property test,scanning electron microscope (SEM). With the addition of PP-g-(GMA-co-St),the interface interaction between PP and PC improved,the tensile strengths were dramatically enhanced by adding PP-g-(GMA-co-St),which indicated that the compatibility of PC/PP blends was significantly improved. The increased interface interactions between PC and PP resulted in enhanced apparent viscosity and decreased sensitivity to the shear flow as well.

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