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PP/EPDM/nano-CaCO_3复合材料的形态和性能
  • 期刊名称:合成树脂及塑料
  • 时间:0
  • 页码:65-68
  • 语言:中文
  • 分类:TQ325.14[化学工程—合成树脂塑料工业]
  • 作者机构:[1]四川大学高分子科学与工程学院高分子材料工程国家重点实验室,四川成都610065
  • 相关基金:国家自然科学基金项目(20874066).
  • 相关项目:动态外场下PC/PE共混体系形态演变与调控
中文摘要:

利用柔和法制备三元乙丙橡胶(EPDM),纳米碳酸钙(nano—CaC03)N.N出物,再分别用两步法和分级注入法与聚丙烯(PP)熔融共混制备PP/EPDM/nano—CaCO3复合材料。当w(EPDM)为25.5%时,分级注入法制备的复合材料形成了分散相EPDM中包覆PP相的多重包覆结构:当w(EPDM)大于16.5%时.分级注入法能明显降低EPDM粒子直径,使EPDM粒子形状规则,分散均匀;两步法制备的复合材料结晶温度和储能模量均比分级注入法高,说明两步法中有更多的nano—CaCO3粒子从EPDM相迁移到PP相中,这与扫描电子显微镜分析结果基本一致。

英文摘要:

The authors prepared pre-extrudate of ethylene-propylene-diene terpolymer(EPDM)/nano-calcium carbonate(nano-CaCO3) by mild mixing method, and then synthesized polypropylene(PP)/EPDM/nano-CaCO3 composite with two-step extrusion or lateral injection extrusion method, respectively. A complex structure of EPDM particles as dispersed phase which contain PP phase was observed in the composite prepared with lateral-injection extrusion method when mass content of EPDM reached 25.5%. The lateral-injection extrusion method endowed the EPDM particles with smaller diameter, regular shape and homogeneous distribution when EPDM content was 16.5%. The crystallization temperature and storage modulus of the composite prepared with two-step extrusion method were higher than those of its counterpart made with the lateral extrusion method, this fact accounted for the migration of nano-CaCO3 particles from EPDM phase into PP phase, as confirmed by the observation of scanning electron microscope.

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