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Novel and Efficient One Pot Condensation Reactions between Ketones and Aromatic Alcohols in the Presence of CrO3 Producing α,β-Unsaturated Carbonyl Compounds
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O623.5[理学—有机化学;理学—化学] TQ174.1[化学工程—陶瓷工业;化学工程—硅酸盐工业]
  • 作者机构：[1]Department of Macromolecular Science, Fudan University, Shanghai 200433, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （NSFC） （Nos. 50825303 and 30890140） and the Ministry of Science and Technology of China （No. 2009CB-930400）.
作者： 李亚男[1], 陈道勇[1]
关键词： 羰基化合物, CRO3, 缩合反应, 芳香醇, 不饱和, 生产, 小说, 酮, one pot condensation reaction, ketone, alcohol, CrO3, α,β-unsaturated carbonyl compound
中文摘要：

我们报导一个新、有效、简单的方法因为准备、不饱和的羰基在 56 瑩由反应加重酉同类和芳香的白酒吗？

英文摘要：

We report a new, effective and simple method for preparing a,fl-unsaturated carbonyl compounds by reacting ketones and aromatic alcohols at 56 ℃ in the presence of CrO3 （CrO3 acts as an oxidant and also a catalyst） for around 10 h. The condensation reactions occurred effectively among a wide combination of ketones and alcohols. The procedure is simple and the yields can be high up to 98%. And a probable mechanism is proposed.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175