目的 :制备立方形锰氧化物高电容超级电容器材料。方法:采用水热结合热分解的方法,制备结构均一的锰氧化物的立方体结构;利用X射线衍射仪(XRD)、扫描电镜(SEM)、透射电镜(TEM)等方法对样品进行了微观表征,使用自制的三电极体系对电极材料进行了循环伏安(CV)、充放电性能和循环稳定性研究。结果:检测结果显示,所制备的立方体结构是由一个个约为10 nm的小颗粒自组装形成的,颗粒之间具有丰富的微孔结构。电化学测试显示在电流密度为1 A/g下,担载量为2 mg/cm2的条件下,电极材料的放电比容量高达318 F/g,其作为正极材料具有比较好的电容特性。结论:此方法制备过程简单,容易工业化生产,该立方形的锰氧化物较适合作为超级电容器的正极材料。
Objective: To prepare cube manganic oxide with super high electrical capacity. Method: The uni-form cube manganic oxide was prepared by a facile hydrothermal method. XRD SEM and TEM are used to eha-racterize the structure and surface morphology. Results: The results show that this hierarchical structure iscomposed of nanopartieles with size of around 10 nm. The electrical capacity material was also studied by CV,charge - discharge and cycle stability curves by three - electrode system. The results of electrochemical testingindicated that the specific capacitance is 318 F/g at current density of 1 A/g with a high load of 2 mg/cm2.Conclusion: These results indicate that this cube manganie oxide is suitable for electrical supereapaeitor materialfor their simple preparation process and easily achieved industrial production.