像暂停的聚合方法被用来 poly 获得有高核心的 /paraffin 蜡 microcapsules 和 micro/nanocapsules 满足的甲基 methacrylate (PMMA ) 。粒子尺寸分发(PSD ) 分析显示 microcapsules 的平均粒子尺寸是 94
The suspension-like polymerization method is used to obtain poly methyl methacrylate (PMMA)/paraffin wax microcapsules and micro/nanocapsules with high core content. Particle size distribution (PSD) analysis indicates that the average particle size of microcapsules is 94 μm, and the size of micro/nanocapsules ranges in 0.1-19 μm. Differential scanning calorimetry (DSC) and thermalgravimetric analysis (TGA) results show that the fabricated paraffin contents in microcapsules and micro/nanocapsules are as high as 89.5 wt% and 80~2 wt%, respectively with good thermal stability. Thermal cycling tests justify that both the microcapsules and micro/nanocapsules have good thermal reliability with respect to the changes in their thermal properties after 1000 thermal cycling. This work pro- vides a novel method to prepare microcapsules and micro/nanocapsules with high core content which may benefit further study on thermal energy storage.