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远青弧菌、硫酸盐还原菌及其混合菌种作用下B10合金的海水腐蚀行为
  • ISSN号:0412-1961
  • 期刊名称:《金属学报》
  • 时间:0
  • 分类:TG178[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]中国石油大学(华东)化学工程学院,青岛266580, [2]中国船舶重工集团公司第725研究所海洋腐蚀与防护国家级重点实验室,青岛266071, [3]中国石油大学(华东)机电工程学院,青岛266580
  • 相关基金:国家自然科学基金重点项目51131008;中国石油大学(华东)创新工程项目CX-1221资助
中文摘要:

采用电化学实验及SEM和EDS分析技术,研究了B10合金分别在无菌和接种了远青弧菌、硫酸盐还原菌(SRB)以及二者混合菌种的海水中的腐蚀行为.结果表明,不同海洋微生物条件下B10合金的腐蚀行为及机制有所不同.远青弧菌通过阻滞氧去极化阴极过程在一定程度上抑制B10合金腐蚀;SRB则通过氢去极化使阳极溶解加速,而生成的粗大颗粒状腐蚀产物Cu2S对基体的保护性不佳,促进了B10合金的腐蚀;而在混合菌种条件下,B10合金腐蚀的阴极过程与仅接种SRB时相似,但阳极溶解形成的腐蚀产物比后者细小且致密均匀,使其阳极极化显著增大,阻滞了试样的进一步腐蚀,其腐蚀电流密度介于2种单一菌种之间.因此在工程实践中,根据实验室单一菌种条件下材料的腐蚀行为来估计和预测在实际微生物环境中材料的腐蚀行为时宜慎重.

英文摘要:

With increasing attention paid to the security issues of onshore engineering structure,corrosion researches of copper alloy were focused on the influence of single bacteria,especially the anaerobic sulfate-reducing bacteria(SRB).However,a part of documents indicated that comprehensive influence of natural bacteria on the copper alloy does exist,and whether the influence of single bacteria could represent the real impact of natural complex bacteria is remaining unclear.Under this consideration,electrochemical measurements,incorporated with surface morphology and composition analysis,were employed to investigate the corrosion behavior of B10 alloy inseawater which was inoculated into Vibrio azureus,SRB and their mixed strains,respectively,in this work.The results showed that these marine micro-organisms could affect the corrosion process of B10 alloy in relatively different ways.Compared with the sterile condition,Vibrio azureus could inhabit the corrosion of B10 alloy to some extent by blocking cathodic oxygen reducing process,while SRB could significantly promote its corrosion by accelerating anodic dissolution of B10 alloy via hydrogen depolarization and forming loose and bulky corrosion products without complete protection.In the mixed microbial medium,SRB multiply rapidly in the local anaerobic environment created by the biological membrane of Vibrio azureus,their interacting changed the corrosive micro-environment on the surface of B10 alloy.The smaller and complicated corrosion products formed in the seawater containing mixed strains obviously performed better than that produced in the medium containing SRB only,giving rise to a significant increase in anodic polarization; at the same time,similar cathodic process was still occurred in the mixed culture.As a result,the corrosion current density of B10 alloy fell in between those detected in two single microbial media.For the practice engineering applications,therefore,the conclusions drawn from single microbe medium should be cautiously and carefully ado

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期刊信息
  • 《金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学协术协会
  • 主办单位:中国金属学会
  • 主编:柯俊
  • 地址:沈阳文化路72号
  • 邮编:110016
  • 邮箱:shxiao@imr.ac.cn
  • 电话:024-23971286
  • 国际标准刊号:ISSN:0412-1961
  • 国内统一刊号:ISSN:21-1139/TG
  • 邮发代号:2-361
  • 获奖情况:
  • 第一、二届全国优秀科技期刊评比一等奖,第一、二、三届国家期刊奖,国家期刊方阵"双高"期刊,第一、二、三届中国科学院科技期刊评比一等奖,中国科学院优秀期刊特别奖,第一、二、三、五届中国科协优秀科技期刊评比一等奖,中国科协精品期刊工程A类、B类,第一、二、三、四、五届中国百种杰出学术期刊,首届出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:26785