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Molybdenum Nanoscrews: A Novel Non-coinage-Metal Substrate for Surface-Enhanced Raman Scattering
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  • 分类:O657.37[理学—分析化学;理学—化学] TB383.1[一般工业技术—材料科学与工程]
  • 作者机构:State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology, Sun Yat-sen University
  • 相关基金:supported by the National Natural Science Foundation of China (Grant Nos. 11474364, 51202300, 51290271);the National Key Basic Research Program of China (Grant Nos. 2013CB933601, 2013YQ12034506);the Guangdong Natural Science Funds for Distinguished Young Scholar (Grant No. 2014A030306017);the Guangdong Special Support Program, the Doctoral Fund of Ministry of Education of China (Grant No. 20120171120012);the Program for Changjiang Scholars and Innovative Research Team in University (Grant No. IRT13042);the Fundamental Research Funds for the Central Universities
中文摘要:

For the first time, Mo nanoscrew was cultivated as a novel non-coinage-metal substrate for surface-enhanced Raman scattering(SERS). It was found that the nanoscrew is composed of many small screw threads stacking along its length direction with small separations. Under external light excitation, strong electromagnetic coupling was initiated within the gaps, and many hot-spots formed on the surface of the nanoscrew, which was confirmed by high-resolution scanning near-field optical microscope measurements and numerical simulations using finite element method. These hotspots are responsible for the observed SERS activity of the nanoscrews. Raman mapping characterizations further revealed the excellent reproducibility of the SERS activity. Our findings may pave the way for design of low-cost and stable SERS substrates.

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