基于0.36BiScO3-0.64PbTiO3(BSPT64)高温压电陶瓷体系,引入Ga2O3并通过传统固相反应法制备了0.36[BiSc(1-x)CaxO3]-0.64PbTiO3(x=0.001、0.003、0.005、0.008、0.01、0.015、0.02)系列压电陶瓷。X射线衍射分析表明Ga^3+取代B位的Sc^3+不影响BSPT64体系的钙钛矿结构。通过对材料介电和压电性能的研究,发现在取代量x=0.01附近,BGSPT64x陶瓷的各项性能表现最优。BGSPT64-0.01陶瓷的压电常数d33、机电耦合系数κp分别为510pC/N和61%,剩余极化强度Pc和矫顽场Ec分别为49μC/cm^2和21kV/cm。研究表明,BGSPT64-0.01陶瓷是一种优良的压电换能器和传感器材料。
Ceramics of 0. 36 [ BiSc(1 -x) GaxO3]-0.64PbTiO3 ( x = 0. 001 , 0. 003,0. 005,0. 008,0. 01,0. 015, 0. 02) are prepared by conventional solid state reactions when Ga2O3 is doped into 0. 36BiScO3-0. 64PbTiO3 (BSPT64) system. The analysis results of X - ray diffraction reveal that Ga^3 + replacing Sc^3 + does not change the perovskite structure of BSPT64. The dielectric and piezoelectric properties are investigated. The results show that BGSPT64 -0.01 has an optimized characterization, i.e. its piezoelectric coefficient d33 ,planar coupling coefficient κp, remnant polarization Prand coercive field Eoare respectively 510 pC/N,61% ,49 μC/cm^2 and 21kV/cm. The research results show that the BGSPT64-0.01 ceramics is a good candidate material for the piezoelectric actuator and transducers.